Volcanic sand taken apart

Photos of sand may be beautiful but their educational value is probably pretty limited. We tend to overlook details if thousands of grains are visible at the same time. So I decided to try another approach with a volcanic sand sample from São Miguel Island in the Azores Archipelago.

This sand contains olivine, plagioclase, and two pyroxenes (diopside and aegirine). This clearly indicates that the sand is the disintegration product of mafic volcanic rocks. There are also lots of volcanic glass and analcime grains. I don’t know whether the latter is a primary mineral or an alteration product of volcanic glass. Analcime is the only zeolite that may directly crystallize from magma.

The presence of both analcime and aegirine give a strong hint that the volcanism in the Azores archipelago is probably alkaline. This term may easily create confusion. Here it means that the magma is enriched in alkaline chemical elements (sodium, Potassium). It has not much to do with brines or bases dissolved in water. Analcime and aegirine both contain sodium.

Most of the components this sand is made of are unstable in the weathering environment. Hence, it has to be pretty immature sand. Some olivine grains are clearly weathered. They are dull yellowish green while fresh olivines are bright green.

Pay attention to the fact that there is absolutely no quartz. Oceanic islands with mafic volcanism are one of the few places where you can see sand without this mineral. Quartz and olivine are often mutually exclusive. Sure, everything may be mixed up in sand but these minerals in normal circumstances do not crystallize from the same body of magma. Magnesium rich olivine forsterite (olivine in this sample is also forsterite) will react with free silica and form pyroxene: Mg2SiO4 (forsterite) + SiO2 (quartz) → 2MgSiO3 (enstatite, one of pyroxenes). This equation means that we may have olivine and pyroxene or pyroxene and quartz but no olivine and quartz together.

Common constituents of volcanic sand.
These are the major constituents of a sand sample collected on the São Miguel Island, The Azores Archipelago, Portugal. The width of the view is 19 mm.
Azores sand
Same grains together as a sand sample. Try to find the minerals shown on the previous photo. The width of the view is 14 mm.

Coral sand from Sint Maarten

Sint Maarten is a sothern part of Saint Martin Island in the Caribbean. It belongs to the Netherlands. Needless to say, weather is generally very nice there and beach sand light-colored. What is the composition of this sand? It is a coral sand. It contains fragments of corals, forams, gastropods, sea urchins, clams, etc.

Sint maarten sand
Carbonate biogenic beach sand from Sint Maarten. The width of the view is 10 mm.

Sint Maarten sand grains
Selected biogenic sand grains picked from the sand. The width of the view is 6 mm.

1. Foram. Homotrema?
2. Coral or calcareous algae?
3. Bivalvia
4. Crustacean shell (crab)?
5. Gastropod, family Caecidae
6. Octocoral spicule
7. Octocoral spicule
8. ?
9. Sea urchin spine
10. Gastropod?
11. Sea urchin spine
12. Sponge spicule
13. Foram

These identifications are by no means certain. I encourage you to let me know if you think you can identify some of the grains shown on the photo.

Colorful sea urchin spines

Sea urchins spines are very common biogenic sand grains. Sea urchins are sometimes called echinoids although it is not precise because sand dollars and few other groups are echinoids as well. However, sea urchins tend to leave behind the most visible and numerous traces. I don’t know how many spines one animal may have but this number definitely exceeds 100. Hence it is no surprise that there are lots of spines in the sand but precious little sea urchin tests. These of course tend to break into fragments which makes finding and recognizing them even more complicated.

Colorful sea urchin spines
Elongated colorful grains are sea urchin spines. The width of the view is 10 mm. Muizenberg, South Africa.

Sea urchin spines are often colorful. Green, white, and purple are very common shades. They are easily recognizable even if the fragments are not elongated because they have very well developed and characteristic strucure. Sea urchins inhabit all oceans. Hence they may be present in both low and high latitude beach sands.

Sea urchin
Alive sea urchin on the seabed near Sardinia. Photo: Marco Busdraghi/Wikimedia Commons.

Sea urchin test
Sea urchin test without spines. Photo: NOAA.

Remnants of bottle messages

Trash thrown into the sea is a global and unfortunately ever-increasing problem. Most of the garbage is plastic because the decay of this material takes enormous time. Another type of resistant trash dumped into the sea is glass.

http://picasaweb.google.com/107509377372007544953/Coll#5852307320112952114
Glass Beach, Kauai, Hawaii Islands. Transparent, green, and brown glass pebbles. Dark grains are fragments of olivine basalt (without olivine which is due to weathering replaced by iddingsite). There are also biogenic grains (forams, mollusks, echinoids, and corals). Although I am somewhat reluctant to say so, but I think we have to admit that even trash can sometimes become beautiful. The width of the view is 20 mm.

A very small part of it may indeed come from castaway sailors sending bottle messages but mostly it is the result of people using sea as a huge garbage dump. Glass is not as visible and annoying in the sea as plastic because it is heavier than water and sinks to the bottom. And rounded glass pebbles can easily be mistaken for some minerals. It may look very similar to quartz, especially if the glass is transparent.

In our particular case the transparent grains are indeed glass pebbles, not quartz. It is easy to distinguish between the two with the help of a polarizing microscope. Unlike quartz, glass has no crystal structure and is therefore dark (showing no interference colors) when placed between the two crossed polarizers of the microscope.

Sea glass has lost its sharp edges because of the tumbling action of waves. It is frequently washed ashore but the concentration of seaglass in the beach sand is usually very low. There are some notable exceptions such as the Glass Beach in Kauai Island or the Glass Beach of Fort Bragg in California. Glass has concentrated there because these places were used as garbage dumps in the past.

Fort Bragg Glass Beach
Glass Beach, Fort Bragg, California. Transparent, blue, and green glass pebbles. There are some biogenic grains (mollusk shells, echinoids) and rock fragments (mostly lithic sandstone). The width of the view is 28 mm.

marine garbage on the Icelandic coast
The majority of trash on the coast is anything but beautiful. Plastic garbage is not only ugly sight but also a serious threat to marine life. The photo was taken in Iceland.

Sand full of life

My last post about the mysteries of sand was successful. I got some useful insight. Here is another photo of seashells picked from a single sand sample.

This time it is from Majorca, Spain. If You know more precisely to which organisms these seashells belonged or think that some of them may be misidentified, don’t hesitate to contact me.

Majorca biogenic sand
Seashells picked from a sand sample collected in Majorca, Spain. The width of the view is 10 mm.

1. Echinoid spines
2. Echinoid spines
3. Echinoid spines
4. Gastropoda
5. Bivalvia
6. Foram
7. Bryozoan
8. Gastropoda
9. Ostracoda
10. Foraminifera
11. Serpulid
12. Foraminifera
13. Scaphopod
14. Foraminifera (could be Quinqueloculina)
15. Agglutinated foram maybe
16. Mollusk shell
17. Foraminifera
18. Bryozoan probably
19. Gastropoda
20. Bryozoan
21. Foraminifera
22. Sponge spicule
23. Foraminifera

Sand full of mysteries

It is much harder than I thought. I am no expert in marine biology but I would really like to know what my sand samples contain. I have turned to several biologists and paleontologists but so far I have received very little useful insight.

Well, now I am turning to You. If you happen to be a marine biologist or know someone who could help me, please let them know of me or my blog. I have some nice material and I am willing to share it here but pictures without explanations are not much worth.

Here are some biogenic fragments picked from a fine-grained sand sample collected in Zakynthos, Greece. I know most of them are foraminifera but there is some other stuff too.

Biogenic grainsZakynthos biogenous sand grains
Biogenic grains from a sand sample collected in Zakynthos, Greece. The width of the view is 7 mm.

1. Spiroloculina (foraminifera)
2. Clam or gastropod shell. Pelecypod?
3. Elphidium (foraminifera)
4. Peneroplis (foraminifera)
5. Ostracoda
6. Sorites (foraminifera)
7. Agglutinated foraminifera? Clavulina or Bigenerina.
8. Peneroplis (foraminifera)
9. Foraminifera
10. Calcareous coralline algae
11. Cibicides (foraminifera)
12. Elphidium (foraminifera)
13. Echinoid spine
14. Peneroplis (foraminifera)
15. Peneroplis (foraminifera)
16. Sorites (foraminifera)
17. Peneroplis (foraminifera)
18. Gastropoda
19. Foraminifera. Homotrema?
20. Echinoid spine?
21. Peneroplis (foraminifera)
22. Gastropoda
23. Mollusk shell. Clam?

Wonders of sand – rounded forams

Sand is full of wonders. There are lots of really nice and unusually large forams in a sand sample from Cyprus.

Forams (foraminifera) are amoeboid protists. They are benthic or planktonic sea creatures (they are not animals) who build calcareous (mostly) tests (or shells) which become biogenic sand grains after the owner of the test dies.

Tests of foraminifera are usually less than 1 mm in diameter but these are almost 2 mm. I am not sure about the genus. It could be Amphisorus but Sorites and Marginopora are possibilities as well.

Take a look at the star sand also. These are forams as well and look amazing.

Foraminifera from Cyprus
Forams picked from the sand sample collected in Paralimni, Cyprus. The width of the view is 20 mm.

Star sand and Sun sand

Foraminifera or more precisely their calcareous tests are very common components of many beach sands.

Lots of so-called coral sands are composed mostly (or in large part) of foram tests. These tests are usually worn out and barely recognizable. Still, some fresh examples of certain genuses look really spectacular. Probably the best example is a star sand from Ryukyu Islands, Japan.

This sand is actually composed of several foram species. Two of the most eye-catching genuses are Baculogypsina and Calcarina. Sometimes they are treated separately and called the Star sand and the Sun sand, respectively.

Below are pictures of selected foram tests picked from a sand sample collected in Hatoma Island (200 km east of Taiwan).

Foram species Baculogypsina sphaerulata
Foram species Baculogypsina sphaerulata. The width of the view is 15 mm.

Foram genus Calcarina
Foram genus Calcarina. The width of the view is 20 mm.

The rare beauty of quartz crystals

Quartz grains in sand may be rounded or angular but they show their crystal faces extremely rarely. There are two good reasons for that.

Quartz is a tough mineral. It is resistant to both physical and chemical attack. But as millions of years pass they eventually obtain more and more rounded shape. Many quartz grains we encounter in beaches or desert dunes may be very old and their crystal faces, if they had them, are long gone.

But there is another and even better explanation. Most quartz grains never existed as beautiful crystals. Quartz is primarily an igneous mineral — it crystallizes out of magma. If the magma body cools, crystals start to form. Most of these crystals belong to the silicate minerals — they contain silicon and oxygen.

First silicates that start to crystallize take in addition to silicon and oxygen other elements such as iron, magnesium, and calcium into their crystal structure. If all these elements are removed from the melt and there is still silicon and oxygen available (it happens in most cases), then the rest crystallizes as pure silicon dioxide which is a mineral we call quartz. Therefore, quartz is among the last minerals to form in a cooling magma body and it has to take the space which is still available between the crystals that have already formed. This space is obviously irregular and provides no opportunity for the crystals to grow as they would like.

But sometimes quartz forms crystals with well developed faces. How is it possible? It can happen if the quartz crystals form in a vug — a crack or fracture in the rocks. It crystallizes out of water that circulates in such cracks. In this case there is nothing to stop quartz crystals to grow just like they want to as long as there is free room to do that.

Quartz from these vugs will be liberated as sand grains when the weathering reaches their host rocks. It should be obvious now that such quartz crystals are very rare in sand. There are some other environments where quartz crystals grow but none of them is a significant source. Below you can see one of these samples. These euhedral (with well developed crystal faces) quartz crystals grew in a gypsum deposit in New Mexico, USA. They are known as the “Pecos diamonds”.

Quartz crystals
Crystals of quartz (the Pecos diamonds) picked from a coarse-grained sand that comes from a gypsum deposit in New Mexico, USA. The width of the view is 15 mm.

Gypsum sand

Gypsum is a relatively rare constituent of sand. An exception is a large dune field in New Mexico White Sands National Monument that is entirely composed of tabular gypsum grains.

Why is gypsum rare in sand? Because it is moderately soluble in water. Gypsum crystallizes out of concentrated solutions — it is an evaporite mineral. It can also quite easily go into solution again. Anything soluble is generally not going to last long in sand. Gypsum sands in New Mexico exist there because this state is not too famous for a wet climate, quite the contrary. The area also has no outlet to the sea which means that gypsum grains that are dissolved in rain water have no escape from the area and eventually may become sand grains again.

Ordinary sand grains made of quartz are the disintegration product of granite, sandstone, or other quartz-containing rocks. The crystals of quartz can be very old. Gypsum grains in the White Sands National Monument are different. They are not the product of disintegration of rocks. These grains are formed in the salty brines which get their high dissolved gypsum from the gypsum containing sedimentary rocks nearby.

White dunes in the
White gypsum dunes of the White Sands National Monument in New Mexico, USA. Photo: davebluedevil/Wikimedia Commons.

Gypsum sand from New Mexico White Sands National Monument
Sand from the White Sands National Monument in New Mexico that is composed entirely of gypsum grains. Width of view 5 mm.