What is sand

Sand is a natural unconsolidated granular material. Sand is composed of sand grains which range in size from 1/16 to 2 mm (62.5…2000 micrometers). Sand grains are either mineral particles, rock fragments or biogenic in origin. Finer granular material than sand is referred to as silt. Coarser material is gravel. Majority of sand is dominantly composed of silicate minerals or silicate rock fragments. By far the most common mineral in sand is quartz. Hence, the term “sand” without qualification is imagined to be composed of quartz mostly. However, sand is a natural mixture which means that it is never pure. By no means can one say that quartz and sand are the same thing. Consolidated sand is a rock type known as sandstone.

Nine sand samples
Colorful sand samples from various corners of the world:
1. Glass sand from Kauai, Hawaii
2. Dune sand from the Gobi Desert, Mongolia
3. Quartz sand with green glauconite from Estonia
4. Volcanic sand with reddish weathered basalt from Maui, Hawaii
5. Coral sand from Molokai, Hawaii
6. Coral pink sand dunes from Utah
7. Volcanic glass sand from California
8. Garnet sand from Emerald Creek, Idaho
9. Olivine sand from Papakolea, Hawaii

Formation of sand

Sand forms mostly by the chemical and/or physical breakdown of rocks. This process is collectively known as weathering. Physical and chemical weathering are usually treated separately, but in reality they usually go hand in hand and it is often difficult to separate one from another because they tend to support each other.

Chemical weathering is much more important sand-producing factor overall. It operates most efficiently in humid and hot climate. Physical weathering dominates in cold and/or dry areas. Weathering of bedrock which produces sand usually takes place in soil. Soil covers bedrock as a thin layer, providing moisture for the disintegration process of rocks.

Rapakivi granite
Weathered rapakivi granite on the coast of Karelia.

Granite is a common rock type and serves as a great example of sand forming processes. Granite is composed of feldspar (pink and white) which decomposes chemically into clay minerals. Another important constituent of granite is quartz (gray). Quartz is very resistant to chemical weathering. It does not alter to any other mineral — quartz is quartz and will remain that way. It eventually goes into solutions but VERY slowly. Hence, disintegrated granite yields lots of quartz grains which will be transported mostly by running water as sand grains. The sample is from Italy. Width of view 21 cm.

Sand arctic Canada
Here is a picture of disintegrated granite (sand sample) from the Canadian Arctic. It is a mixture of angular quartz and feldspar grains. The abundance of feldspar and angularity of the grains is a strong hint that this sand sample has not been transported long from its source area and the climatic conditions can not be humid and hot. Width of sample 20 mm.

http://picasaweb.google.com/107509377372007544953/Coll#5823755327463125186
Here is an example of mature sand sample from USA (St. Peter Sandstone from the Ordovician Period). It is composed of almost pure and well-rounded quartz grains. This is what eventually happens if we give enough time for the nature to chemically destroy most other minerals that were present in the source rocks. St. Peter Sandstone has seen much increased demand in recent years because it is well-suited for fracking purposes. Width of view 20 mm.

http://picasaweb.google.com/107509377372007544953/Tenerife#5824008633671352338
But what happens to other minerals? They are either converted to new stable minerals in atmospheric conditions (mostly clay minerals) or get carried away as ions in hydrous solutions and end up in the oceans. So these are freshwater rivers that carry ions to the sea and make it salty. There is a nice amount of irony in it. Clay minerals are carried by rivers also and we usually refer to this load of clay as mud. There is a muddy temporarily dry riverbed on the picture. Mud that covers these rocks is a mixture of clay minerals, fine sand, silt, and water. Barranco de las Augustias, Caldera de Taburiente, La Palma.

Composition of sand

Sand is a residual material of preexisting rocks. It is therefore composed of minerals that were already there in the rocks before the disintegration commenced. However, there is one important aspect — sand occurs in a harsh environment where only the strongest survive. By “strongest” I mean the most resistant to the weathering processes.

Quartz is one of these minerals (list of minerals in sand) but not the only one. It is so dominant in most sand samples because it is so abundant. 12% of the crust is composed of it. Only feldspars are more abundant than quartz. (Here is more information about the composition of the crust).

Relatively rare minerals like tourmaline, zircon, rutile, etc. are also very resistant to weathering, but they rarely make up more than few percents of the composition of sand. These minerals are collectively referred to as heavy minerals.

Beach sand from Sri Lanka that contains lots of heavy minerals. Most of them are reddish spinel and garnet grains. Width of view 20 mm.

Heavy minerals may sometimes occur in sand in much higher concentrations. This is usually a result of hydrodynamic sorting. Either sea waves or river flow sort out heavier grains and carry lighter ones away. Such occurrences are known as placers and they are often used as a valuable mineral resource. Minerals that are often extracted from placer deposits are gold, cassiterite, ilmenite, monazite, magnetite, zircon, rutile, etc.

http://picasaweb.google.com/107509377372007544953/Coll#5822980311210985986
Concentrate of zircon extracted from beach sand in South Africa. Width of view 12 mm.

Quartz definitely dominates in most sandy environments, but it is usually accompanied by feldspars. Feldspars are only moderately stable in atmospheric conditions, but their overall volume in common rocks is huge. More than half of the whole crust is composed of feldspars. Other common rock-forming minerals like amphiboles and micas also frequently occur in sand. Some common minerals in certain rocks like olivine and pyroxenes occur in sand in smaller volume because their resistance to weathering is nothing to brag about.

However, there are enough sandy beaches that are mostly composed of pyroxenes and olivine with magnetite. How can anything like that happen? Such beaches with a black sand occur in volcanically active areas where quartz-bearing rocks are missing. Pyroxenes and olivine are common minerals in mafic rocks like basalt. Black sand is a typical phenomenon of oceanic volcanic islands where granite is missing and felsic quartz-rich rocks rare.

Basalt pebbles
Basalt pebbles near the southern tip of La Palma slowly transforming into black sand typical to volcanic oceanic islands.
Black sand forms in volcanic islands if quartz and biogenic grains are not available. Here is a basaltic cliff and black sand on La Palma, Canary Islands.

Siesta Key Beach
Siesta Key beach sand in Florida, on the other hand, is composed almost exclusively of quartz grains and is therefore as white as it possibly can be.

Most sand samples consist of sand grains which are composed of a single mineral — quartz grains, feldspar grains, etc. But sand may also contain grains that are aggregates of crystals i.e. fragments of rocks (known also as lithic fragments). Lithic sand is usually immature and it also tends to form when rocks are very fine-grained. Granite usually disintegrates into distinct mineral grains, but phyllite and basalt for example are often so fine-grained that they tend to occur in sand as lithic fragments. Lithic fragments are also common in regions where erosion is rapid (mountainous terrain). You can find more about immature sand in this article: Sand that remembers the rock it once was.

Caption
Fragments of micaceous fine-grained metamorphic rocks (phyllite, mica schist) from Canada. Width of view 20 mm.

Sometimes sand contains new minerals or mineral aggregates that were non-existent in the source rocks. Notable example is a clay mineral glauconite which forms in marine sand and gives distinctive dark green color to many sand samples. In some instances glauconite in sand may come from disintegrated glauconitic sandstone nearby, but eventually it is of marine origin anyway.

Glauconitic sand from France. Width of view 20 mm.

There are many other strange sand samples that require special formation conditions. One good example is sand in New Mexico that is composed of pure gypsum. I have written about it here: Gypsum sand. Sand with such a composition is odd and unexpected because gypsum is an evaporite mineral. It was precipitated out of hyper-saline water and it goes easily into solution again. Hence, it can only survive in dry conditions with no outlet to the sea. Halite, which is even more soluble than gypsum, is also known to form sand in special conditions.

Volcanic ash is usually treated separately, not as a type of sand. Probably because we humans tend to create artificial barriers and classification principles. We think that sand is a collection of sedimentary particles, but sedimentary and igneous rocks are two different worlds. In reality, this is more complicated because there is every reason to say that volcanic ash grains (and other pyroclastic particles like lapilli and volcanic bombs) are also sedimentary particles because they got deposited on the ground not much differently than sand grain in a dune does. Volcanic ash and sand have even comparable classification principles — volcanic ash is a pyroclastic sediment with an average grain size less than 2 millimeters. Hence, volcanic ash is a volcanic analogue of sand and silt.

Volcanic ash from St. Helens is composed of pumice fragments and mineral grains. Width of view 20 mm.

Third major and versatile component of sand (two others were mineral grains and lithic fragments) are grains of biogenic origin. Biogenic sand is composed of fragments of exoskeletons of marine organisms. Common contributors are corals, foraminifera, sea urchins, sponges, mollusks, algae, etc. Such sand is usually known as coral sand although in many cases it contains no coral fragments at all. Biogenic sand is light-colored and widespread in low latitude marine beaches although there are exceptions. Corals indeed live only in warm water, but many other taxons can do well in colder climate (coralline algae, clams, some forams). Most biogenic sand grains are calcareous and provide material for limestone formation. Most limestones are former calcareous muds deposited on the seafloor.

Sometimes sand contains or is entirely composed of well-rounded carbonate grains that are not fragments of dead marine organisms. These grains are ooids that also require special formation conditions.

http://picasaweb.google.com/107509377372007544953/Coll#5823755205105895394
Biogenic sand from Tuamotu is mostly composed of forams. Width of view 20 mm.
http://picasaweb.google.com/107509377372007544953/Rocks#5790668029504177410
Ooid sand from Cancún, Yucatán, Mexico. Width of view 5 mm.

Sand does not need to be a pure collection of either mineral, lithic, or biogenic grains. In many cases two of them and sometimes even three are mixed.

http://picasaweb.google.com/107509377372007544953/Coll#5823755129541132050
Mixture of mafic volcanic rocks and various biogenic grains in a sand from the Azores archipelago. Width of view 20 mm.
http://picasaweb.google.com/107509377372007544953/Coll#5823755175156240642
Mixture of dark-colored volcanic rocks, worn-out biogenic grains, and some silicate grains from Jeju-do Island, South Korea. Width of view 20 mm.

Texture and transport of sand

Geologists describe sand by measuring the roundness of grains and the distribution of grain sizes. By doing that they hope to shed some light on the origin of the grains being measured. Roundedness usually gives information about the length of transport route and distribution of grain sizes helps to determine from which environment these grains come from. River sand is usually poorly sorted and compositionally immature. Beach sand is more rounded and eolian dune sand is generally well sorted.

http://picasaweb.google.com/107509377372007544953/Coll#5823755135218064002
Poorly sorted river sand from Sikkim, India. Width of view 20 mm.

Desert sand from Sahara
Eolian sand from the Erg Murzuk, Libya. Dune sand is generally well sorted (grains are similar in size). Width of view 15 mm.

The average size of grains is determined by the energy of the transport medium. Higher current velocity (either stream flow or sea waves) can carry heavier load. Coarse-grained sediments therefore reveal that they were influenced by energetic medium because finer material is carried away.

http://picasaweb.google.com/107509377372007544953/Conglomerate#5777284961325139474
Sometimes river flow is so energetic that sand grains are all carried away and only large rounded stones remain. Such lithified deposits of former riverbeds are known as conglomerates. Photo taken in Cyprus.

Sand is mostly transported by rivers, but average sand grains are too large and heavy for average river to carry them in suspension. Hence, sand grains tend to move in jumps. They are lifted up by more energetic current and settle out when current velocity decreases and then wait for the next jump. This mode of movement is known as saltation. Average silt grain moves differently. It is light-weight enough to be carried in suspension for a long time and this is actually one of the most important reasons why we treat silt separately from sand.

Most sand grains carried by the rivers are eventually deposited at the rivermouths where the current velocity suddenly drops. Then sea waves (longshore currents) take over and carry sand along the coastline. Sand grains carried by the rivers are also deposited on alluvial flood plains and point bars (inside bend of streams where current flow is the slowest).

Sand is also transported by wind, ocean currents, glaciers, turbidity currents, etc. Moving sand forms landforms like ripples and dunes.

http://picasaweb.google.com/107509377372007544953/Tenerife#5824070032354494290
Wave ripples on a tidal flat in Ireland.
http://picasaweb.google.com/107509377372007544953/Tenerife#5824070025234254082
Dunes of Maspalomas on Gran Canaria.
http://picasaweb.google.com/107509377372007544953/California02#5867497002039417346
Sand dunes near Stovepipe Wells, Death Valley (Mesquite Dunes).

Sand dune in Moroccan Sahara
Sand dune in Sahara (Morocco) on a windy day.

Further reading

Pettijohn, F. J., Potter, P. E. & Siever, R. (1973). Sand and Sandstone. Springer
Siever, R. (1988). Sand, 2nd Edition. W H Freeman & Co.

Colors in sand

Sand can be unbelievably colorful. Most of us are familiar with tan, orange, yellow and red colors but the range of colors that occur in sand is almost limitless. In this post I will show some compositionally interesting sand samples and explain briefly which constituents are responsible for these colors.

This is not the most usual stuff we used to play with in a sandbox. Most sand samples shown here are collected from beaches all over the world (Hawaii, Caribbean, Turkey, France, Sri Lanka, etc.) but some are not entirely natural. Sometimes sand contains so much interesting minerals that it is mined as a mineral resource and purified after that. Let’s take a closer look one sand sample at a time.
Olivine
Green mineral is olivine. It is a common mineral in dark-colored igneous rocks like basalt. Papakolea, Hawaii. Width of view 20 mm.
It is a typical coral sand that is widespread in the Caribbean. Pink grains are forams. White is a mixture of corals, forams, mollusks, etc. San Andrés Island, Colombia. Width of view 20 mm.
Obsidian from Hawaii. Such sand forms when lava flows into the sea, disintegrates violently and cools so rapidly that crystals have no time to form. This is natural basaltic glass. Width of view 20 mm.
Garnet is a very common component in many sands and sometimes forms beautiful reddish heavy mineral concentrates. Sand sample is from Australia. Width of view 20 mm.
Sulfur occurs as a native mineral around fumaroles in volcanically active areas. These sulfur grains come from Iceland. Width of view 20 mm.
Sodalite is a relatively rare magmatic mineral. This beautiful sand sample is a mixture of sodalite and dolomite and comes from a mine in Namibia. Width of view 20 mm.
Glauconite is a clay mineral that forms distinctive pellets and frequently occurs in beach sand. This sample is unusually rich in glauconite and comes from France. Width of view 20 mm.
What makes volcanic ash gray? It is actually a mixture of differently colored grains. Pumice and felsic mineral grains (quartz, feldspar) are usually light-colored but most volcanic ash samples also contain mafic crystals (hornblende, pyroxene, etc.) that add darker hue which makes typical volcanic ash look grayish. This sample was collected just one day after the eruption of St Helens in 1980. Width of view 20 mm.
Several beaches claim to have the whitest sand in the world. I am not aware if the shore of Lake Salda in Turkey is among them but it has reason enough. Its sand is composed of snow-white mineral hydromagnesite — a product of hydrothermal reactions. To be honest, this sand also contains few fragments of greenish serpentinite but I removed these grains to make the sand look really white. Width of view 20 mm.
Volcanic black sand from Martinique. It is mostly composed of greenish elongated pyroxene and equant black magnetite crystals. Width of view 12 mm.
Heavy mineral sand from Sri Lanka which contains lots of intensely colored spinel grains. Width of view 20 mm.
Dirt from a copper mine dumps in Namibia. Such bluish green color is typical to weathering products of copper ore like malachite, chrysocolla and chalcophyllite. Width of view 20 mm.
Volcanic glass from California. Reddish color is an indication of weathered iron (mineral hematite). Width of view 20 mm.
This sand sample is composed of ordinary stuff — quartz. It is hematite again that gives reddish color to quartz grains but this time hematite only covers the grains as a very fine-grained pigment. Sand sample is from Australia. Width of view 20 mm.
This time it is not so much about color. Small platelets are mica (brown biotite and gray muscovite) flakes that act as small sparkling mirrors in many sand samples. In this sand samples from France these mica flakes are unusually numerous. Width of view 20 mm.
These bluish grains are small cordierite crystals. Cordierite is a mineral that occurs in metamorphic rocks. I made this sand sample by crushing rock sample that was composed of fine-grained cordierite. Width of view 20 mm.

Is Papakolea the only green beach

The famous Green Sand Beach in Hawai’i is also called Papakolea or Pu’u Mahana Beach. As much as I know it really has few competitors in terms of purity and freshness of the olivine sand. However, it is definitely not correct to say that it is the only one. The absence of evidence is not the evidence of absence. There is no need to go very far from the Big Island. Diamond Head is a tuff cone in Oahu that constantly feeds the sand beach right next to it with fresh olivine. The sand there is not as bright, but it is definitely composed mostly of olivine and it is green.

Is Papakolea the only green beach
Papakolea beach in Hawaii.

http://picasaweb.google.com/107509377372007544953/Hawaii#5881089836017624546
Layered tuff exposure right next to the beach that is the source material of olivine.

Diamond Head sand
Sand sample from Diamond Head Beach in Oahu. White grains are biogenic fragments (corals and forams). The sand is not as bright as are the sample from Papakolea but it is still clearly greenish. Width of view 11 mm.

Papakolea olivine sand
Olivine sand collected near the southern tip of Hawaii. It is from a tiny cove on the coastal trail, not from the beach itself where the grains tend to be duller green. Width of view 10 mm.

It is interesting to take a look at the Pu’u Mahana and Diamond Head volcanoes. There are some striking similarities. They are both located right next to the beach. They both contain lots of olivine. They are both composed of easily erodable pyroclastic sediments. They are both high and steep which speeds up the erosion.

Diamond Head and  Puu Mahana
Pu'u Mahana on the left and Diamond Head on the right. Images taken from Wikimedia Commons: jonny-mt (Pu'u Mahana) and Brian Snelson (Diamond Head).

Why is this needed for the green sand beach to form? Because olivine is unstable mineral at the atmospheric conditions. The transport route needs to be short and erosion fast to ensure that most of the olivine makes it to the beach and there is a constant supply of fresh material.

All right, we have Diamond Head Beach in addition to Pu’u Mahana but it is still only two and both of them are Hawaiian beaches. It may come as a surprise to many but olivine is not rare in sand. I would even say that it is an essential component of sand in many oceanic islands or volcanically active regions. Canary Islands, Iceland, Galápagos Islands, and Cape Verde are just a few names where olivine is a common constituent of many beach sands.

Olivine sand from Sivuqaq
Sand sample containing lots of olivine from Ivgaq, St. Lawrence Island, Alaska. Width of view 15 mm.

I especially love a sand sample from the St. Lawrence Island in the Bering Sea. The climate there is not quite comparable to the Caribbean. That is perhaps the most important reason why this island is not very popular among tourists. The local Yupik people are quite protective about their island as well but I am lucky to know two of them. They sent me a very nice sample from the northern coast of Sivuqaq (St. Lawrence Island in Central Siberian Yupik). This sand sample is not as green as are the samples from Hawai’i because it contains lots of lithic material but olivine definitely dominates among the single minerals and gives greenish hue to the sand.

This greenish sand is composed of almost pure olivine and is a result of weathering of dunitic rocks. Gusdal quarry, Norway.

Parrotfish makes sand

Parrotfish
Parrotfish on North coast of East Timor. Photo: Nick Hobgood/Wikipedia.

If you love sausages, you should never try to find out how it is made. The same applies to many other things as well. If you love the idea of sunbathing in the Caribbean, you should consider skipping this post.

Biogenic or coral sands found on the seashores of tropic beaches are largely composed of bits and pieces of coral, calcareous algae, foraminifera, gastropoda, sea urchins, etc. Much of this material was rasped from the coral reefs by brightly colored parrotfish. They grind the pieces of corals which then goes through their digestive system to get deposited on the shallow seafloor as calcareous sand grains.

Most parrotfish actually do not feed on corals. They are looking for algae that are inhabiting coral reefs. One might think that parrotfish are a threat to the coral reef ecosystem but it is not true. They actually help corals by not letting algae to choke them.

Parrotfish are very important agents of bioerosion. One parrotfish can make 90 kg of coral sand a year. Parrotfish depend on coral reefs just as coral reefs depend on them. Coral reefs in many parts of the world are not doing well recently, and the same applies to parrotfish as well. They are not seriously endangered, but the future with overfishing, global warming, pollution, and ocean acidification promises not much good to them.

Here is a short video of sandmaking process:



Brain games with sand grains

Sand grains are not uniform in size. The minimum diameter of a sand grain is only 62.5 micrometers or 0.0625 millimeters while the upper limit of a sand grains diameter is 2 millimeters. It is common knowledge but why such numbers? One may say that you simply have to draw the border somewhere in order to be able to differentiate sand from silt or gravel. So are these numbers completely arbitrary? Yes and no. Exact numbers are definitely arbitrary. They are determined by the logarithmic scale which also determines the borders between fine, medium, and coarse sand.

How the smallest sand grain compares to the largest
The gray circle resembles the upper limit of a sand grains (very coarse) size while the smallest red circle resembles the smallest. Black, blue, green, and yellow are the upper borders of coarse, medium, fine, and very fine sand grains respectively. The graph is to scale.

However, this classification scheme is chosen to make as much sense in geology as possible. It reflects the movement of sand grains in water. In the river water, the sand grains are not carried in the suspension. They tend to move in jumps — running water occasionally lifts sand grains up but is not able to carry them far. Sand grains settle again and wait for the next jump. Such mode of movement is called saltation and it is especially characteristic to sand grains. Gravel just rolls on the river bed while silt is usually carried in the suspension.

Sure, it depends on the speed the river water is running. Sometimes (in the fast moving mountain streams) granules saltate as well. And sometimes the river water is not capable of lifting sand grains up even temporarily. Nature doesn’t classify. It has no need for it. But we humans desperately need the classification schemes in order to categorize things and try to make some sense of the world surrounding us. Therefore, no classification scheme is perfect and the one used now is by no means the only one possible.

It is perhaps rather difficult to imagine how different can two grains be if one of them has a diameter of only 62.5 micrometers while the other is 2000 micrometers or 2 millimeters thick. The first one is barely visible while the other is as big as the head of a match. How much is one bigger than the other? It should be simple, we just divide 2000 with 62.5 and get the result of 32. However, such a result may be mathematically correct but it makes no sense. The true measure of a grain size is its volume. After all, whether the river water is capable of carrying the grain depends on the mass and volume of the grains, not on the diameter.

If we assume that our grains are perfect spheres, then the bigger one has 32,768 times larger volume. That’s a huge difference and obviously has to significantly influence the behavor of the grains.

How much one sand grain weighs? Let’s assume that we are dealing with quartz grains. Quartz has a density of 2.65 grams per cubic centimeter. A grain with a diameter of 2 millimeters makes up only little more than four thousands of a cubic centimeter, and it weighs approximately 0.011 grams. I am not giving the mass of a smaller grain, the number would be ridiculously small but you can easily calculate it by dividing 0.011 with 32,768.

Now we know that even the largest sand grains are lightweight. How about the number of grains that we can fit into a container with a definite volume, let’s say 1 cubic centimeter? In order to calculate that, we need to know how many grains we can press into this container. Theoretical calculations show that if the grains are placed irregularly, you can not achieve better packing than about 63%. It means that about 37% of your container will be filled with air, water or something else. It makes up the pore space volume which is a very important metric if we try to calculate, for example, how much crude oil a sandstone layer can contain. Simple calculation yields a result that 1 cubic centimeter can contain 151 sand grains with a diameter of 2 mm and 4,959,645 sand grains with a diameter of 62.5 micrometers.

Most sand collectors prefer to have at least 30 ml of sand per sample. I am an exception because I am satisfied with much less than that. Here are some calculations why this is the case. Let’s assume that average sand grain has a diameter of 250 micrometers (this is a borderline between fine- and medium-grained sand). If you have 30 ml of such sand, then you have 2,324,833 sand grains. Do you really need that many if your goal is to get a general overview of the sand samples composition? Definitely not. Even one hundredth of that is good enough. That is the basis of my claim that if you have a very interesting sand sample but can only send one gram, I would still be happy. It is more than I need.

Can we try to estimate how many sand grains are there in the whole world? Well, no one ever counted them but I think we can make some very rough estimations. There are approximately 200 million cubic kilometers of continental sediments. Assuming that about fourth of it is sand, the total volume of sand is perhaps 50 million cubic kilometers. If we assume that the average sand grain has a diameter of 250 micrometers, then we have approximately 4 x 1027 sand grains in the crust.

This is a really huge number. I remember Carl Sagan once said in his television series Cosmos that there are perhaps more stars in the Universe than there are sand grains on all of the beaches. That may be true but beaches are not the only places where sand can be found. If we calculate the number of all sand grains covering the Crust, I think the sand grains still have the last laugh.

Grain size (µm) Aggregate name Volume difference No. of grains in 1 cm3
62.5 Very fine sand 1 4,959,645
125 Fine sand 8 619,956
250 Medium sand 64 77,494
500 Coarse sand 512 9687
1000 Very coarse sand 4096 1211
2000 Gravel 32,768 151

Silica and sand

What is silica? How is it related to sand? What does it mean that silica sand is made of quartz? It is not difficult to answer these questions but unfortunately the websites I checked contained some erroneous information which needs to be sorted out.

Sandstone in Tabina quarry
Siliceous Devonian sandstone in Estonia.

Silica or silicon dioxide (SiO2) is a chemical compound consisting of one silicon and two oxygen atoms. Quartz is a common mineral with the same chemical composition but quartz and silica are not synonyms. Specific minerals always have a definite crystal structure while chemical compounds have no such restriction — just like every piece of carbon is not a diamond. Quartz is made of silica but so are also cristobalite, tridymite and few other minerals (polymorphs of silica). They are collectively referred to as silica minerals.

Quartz is the most common sand-forming mineral. However, it is not the most common mineral in the crust. That honor goes to feldspars. If the particular sand deposit contains almost nothing but quartz, we often call it a silica sand. Such sand deposits are said to be mature because other rock-forming minerals are already broken down by the weathering process leaving only the super-resistant quartz as a residue. Silica sand is a mineral resource. It is mined mostly for glass-making. Another major use of sand is a concrete production but that does not need sand to be as pure.

Some beautiful beaches are made of silica sand. Beach of Siesta Key in Florida is especially famous for its white sand. Not all white sands are made of silica, though. White Sands National Monument in New Mexico is a dune field which is composed of sand made of gypsum. There are lots of light-colored beach sands around the world but many of them (especially in low latitudes) are made of small pieces of corals and other sea creatures. This sand is calcareous (composed of calcium carbonate) but some biogenic grains are siliceous as well. For example radiolarians (ameoboid protozoa) and diatoms (algae) have siliceous shells.

Sometimes sandstone is said to be siliceous. What does that mean? It may be a sandstone which is cemented by the silica minerals quartz or chalcedony (cryptocrystalline quartz) or it could be a sandstone which is composed predominantly of silica minerals (although sometimes feldspars are included). So you really need to dig deeper and ask critical questions if someone is talking about a siliceous sandstone as its meaning is not immediately obvious.

Siesta Key Beach
Beach sand in Siesta Key, Florida is almost pure silica sand (composed almost exclusively of quartz grains).

What is black sand

Black sand is sand that is black in color. It seems to be very simple. But what is behind this concept? How is this type of sand formed? What is it made of? There is no single and easy answer to these questions because there are a number of different dark sand grains that can form black sand and hence there are several different ways how black sand can form.

Black volcanic beach sand
Black sand on a volcanically active oceanic island. Puerto Naos, La Palma, Canary Islands.

The realm of black sands can be broadly divided into two parts, both of them having subdivisions. The most widespread type of black sand is composed of volcanic minerals and lava fragments. Such sands are especially common on the coasts of volcanic islands (Hawai’i, the Canary Islands, the Aleutians, etc.).

Black sand beaches are black because many volcanic minerals and rocks are dark-colored. Common rock types of volcanic islands are basalt (black when fresh), andesite (usually dark gray) and volcanic glass (often black in color). The minerals that give black color to these rocks are predominantly pyroxenes (mostly augite), amphiboles (mostly hornblende) and iron oxides (mostly magnetite). Such sands are heavier than ‘normal’ light-colored sands and become very hot on a sunny day. Dark color and heavyness are both caused by high iron content. Iron gives black color to most minerals because it absorbs light very well and it is also heavy.

Black sand on the Reykjanes Peninsula
Black volcanic sand on the Reykjanes Peninsula in Iceland.

Black sand on La Palma
Black sand on the western coast of La Palma, Canary Islands.

Basalt cobbles on the beach
Basalt is the most common source rock of black sand. Photo taken near the southern tip of La Palma.

Black volcanic sands may contain many non-black grains like green olivine crystals, reddish (usually because of weathering) volcanic rocks, light-colored quartz (when the source area is continental) and carbonate biogenic grains (coral sand). Most volcanic minerals are not very stable. They decompose pretty rapidly. These sands are said to be compositionally immature (mature sands are composed of quartz and other minerals very resistant to weathering). They also contain unusally high content of lithic (rock) fragments which have not broken up yet to form a sand composed of individual mineral grains.

Volcanic minerals in beach sand of Martinique.
Fine-grained volcanic beach sand from Martinique. Green prismatic mineral is augite. Black is magnetite. Width of view 7 mm.

Black sand composed of volcanic glass.
Black beach sand composed of volcanic glass. Punalu’u Beach in Hawai’i.

Another type of black sand occurs mostly in continental settings. It is heavy mineral sand. Heavy minerals are minerals which have a specific gravity above 2.9. There are almost all colors present among the heavy minerals but they seem to be dark compared to usually light-colored quartzose sand. Heavy mineral sands are usually composed of minerals that are relatively resistant to weathering. Such minerals are tourmaline, magnetite, garnet, rutile, ilmenite, zircon, epidote, staurolite, etc. Heavy minerals are in most cases disseminated among the light-colored (and usually much larger) quartz grains but in certain conditions they tend to accumulate.

You probably have seen dark stripes on a sandy beach which may even be mistaken for an oil pollution. These streaks are composed of tiny gems that were carried high on the beach either by big waves or streams but they successfully managed to avoid flowing back with the receding waves because of their above average density. The most common heavy minerals forming black sands are perhaps magnetite, garnet and epidote. They are widespread enough in the rocks and resist weathering moderately well. They are more resistant than typical minerals of volcanic black sands (olivine, pyroxene, hornblende) but not as resistant as rutile, tourmaline, and zircon. But the latter three never make up the bulk of rocks and therefore are rarely very concentrated in sand.

Heavy minerals in beach sand
Heavy minerals forming black stripes in light-colored sand. White Park Bay, Northern Ireland.

magnetite grains aligned in the external magnetic field
Magnetite grains in the presence of a strong external magnetic field. There is a neodymium magnet placed beneath the sample. Magnetite crystals are from Talofofo Beach, Guam, USA. Width of view 10 mm.

Greensand and green sand

Greensand is a sand or sandstone which owes its unusual color to a mineral glauconite. Glauconite is mixed with other sand grains in all possible proportions. Glauconite grains are usually rounded and dark green in color. Glauconitic sandstones are marine in the majority of cases. Many greensand formations seem to have formed either during the Cambrian or Cretaceous Periods.

Baltic Klint near Paldiski
Baltic Klint in Estonia (near Paldiski, Pakri Peninsula). It is composed of limestone (topmost layer), glauconitic sandstone (greensand), kerogene containing shale (all Ordovician) and a phosphatic Cambrian sandstone.
Closeup of a greensand (glauconite sand) from France. Width of view 20 mm.

However, greensand is not the only green sand in existence. There are several green minerals and in certain cases they may be abundant enough to give green color to the sand. Most famous example is definitely olivine. Green sand beach near the southern tip of Hawaii Island (Papakolea Beach) is world-famous but greenish beach sands containing lesser amount of olivine are not uncommon in volcanically active areas.

Is it all? No, there are a number of other green minerals. Malachite, chlorite, epidote and serpentine are all responsible for the green color of some sand samples in specific locations. But these cases are really specific and spatially very confined.

Olivine
Green mineral is olivine. It is a common mineral in dark-colored igneous rocks like basalt. Papakolea, Hawaii. Width of view 20 mm.
Serpentine sand from Corse, France.
Epidote sand from a mine in Nevada, USA.
This greenish sand is composed of almost pure olivine and is a result of weathering of dunitic rocks. Gusdal quarry, Norway.
Is Papakolea the only green beach
Papakolea beach in Hawaii.

Sand minerals

Sand is a mixture of different materials. You will find more in the post What is sand. Here is an overview of minerals which are the most common sand constituents. Most minerals may occur as sand grains somewhere. So do we have to cover thousands of minerals here? No, we really need to know less than 50 of them to have a reasonably good overview of all the likely possibilities. Other minerals are rare in sand or are found only in specific locations. Mineral identification is so much easier if you know what is the range of possibilities. The following list of minerals in sand is here to help you achieve just that.

Quartz

There is no other mineral that is as important in sand as quartz. It is really almost everywhere and forms the bulk of sand composition in most cases. Pure quartz is transparent but quartz can have almost any color. The grains are usually rounded and they may be covered by a very fine hematite pigment which gives them a rust-colored appearance. Why is quartz so common in sand? It is a widespread rock-forming mineral and it is also extremely resistant to weathering. Quartz has no cleavage. So we never see planar surfaces on fresh fractured grains. Rocks that contain lots of quartz are sandstone, quartzite, gneiss, granite, and many others.

Chalcedony

Chalcedony is composed of microcrystalline quartz and moganite (there is a slight structural difference between them). It is so fine-grained that individual crystals are impossible to see with a naked eye. Even light microscope is of little help. Chalcedony is formed by the crystallisation of silica gels. It is common cementing material in sedimentary rocks. Chert (rock type) is a fine granular microcrystalline quartz (may also contain moganite).

Sanidine

Sanidine is one of feldspars which are very important rock-forming minerals. Feldspars make up more than half of the composition of the crust. Sanidine itself is definitely not the most common among them. It occurs primarily in volcanic rocks (rhyolite, trachyte, phonolite). We have the best chances to encounter sanidine in volcanic sands of felsic composition. Sanidine is one of K-feldspars (Potassium-rich feldspars). Other common K-feldspars are microcline and orthoclase which are more frequently found in sand.

Orthoclase and microcline

Common K-feldspars but they are not as resistant to weathering as quartz. K-feldspars disintegrate to clay minerals. It may be quite difficult to differentiate feldspars from quartz but they generally appear to be more blocky. Feldspar grains may have planar cleavage surfaces and they often show signs of weathering. K-feldspars are commonly white, yellow or pink in color. Microcline generally forms deeper in the crust than orthoclase but it is pretty complicated task to differentiate one from the other. K-feldspars are the most important building blocks of granite.

Plagioclase

Plagioclase feldspars are definitely the most widespread feldspars overall but their resistance to weathering is not good. Plagioclase decays faster than K-feldspars. We have the best chances to see plagiocalse containing sand in volcanically active areas where fresh sand rich in volcanic minerals is abundant. Or in areas where the rocks are nearby and rich in this mineral (granodiorite, tonalite). Plagioclase crystals are often elongated. They are usually different shade of gray in color. Plagioclase is a common mineral in mafic igneous rocks (basalt, gabbro).

Muscovite and biotite

These minerals are two of the most common mica varieties. Micas are very easily recognizable because they occur as very thin and flexible flakes. Sometimes larger blocks of mica occur but they can be split into an almost endless number of ultrathin layers. Muscovite is generally colorless while biotite is brown or black. Both muscovite and biotite are common rock-forming minerals. They are most common in river sands. Wind-blown (eolian) sands generally contain much smaller amount of micas.

Glauconite

Glauconite is somewhat different from most other minerals discussed here because it is not formed from magma nor is it created during the metamorphism of existing rocks. It forms through the sedimentation process as rounded green pellets in marine sediments. Glauconite is the principal component of greensands in which it forms a mixture with quartz.

Clay minerals

Clay minerals themselves are not sand-forming minerals. They can not be because their size is not large enough to be considered sand. However, they are often present in sand as mud (when wet) or dust (when dry). Beach sands are generally free of dust and so are eolian deposits. Dust is present in many river and especially inland sand samples. Most clay minerals are the weathering product of feldspars but many other common minerals also have a destiny to become clay.

Pyroxene

Pyroxenes are important rock-forming minerals but they are unstable in the weathering environment. Therefore we can usually see them in immature sediments of volcanic origin. Pyroxenes give black color to basalt. Volcanic sands are black because of pyroxene and some other dark-colored minerals of magmatic origin. The most abundant member of pyroxene group is augite. Not all pyroxenes are black. Some are colorful or transparent but they occur rarely. Pyroxene grains are usually elongated.

Amphiboles

Amphiboles are elongated as well as pyroxenes and generally also black or greenish. They are closely related to pyroxenes. Amphiboles endure weathering somewhat more successfully and are therefore not as rare in sands. The most common amphibole is hornblende. Amphiboles tend to have a stronger luster than pyroxenes have. Amphiboles are common minerals in igneous (diorite) and metamorphic (amphibolite) rocks.

Pumpellyite

Pumpellyite probably occurs in sand more often than reported because it is usually misidentified as epidote (these two are actually related). Pumpellyite is formed in metamorphic rocks (mostly glaucophane schist) and hydrothermally altered mafic igneous rocks (basalt). Pumpellyite is usually green or bluish green in color.

Epidote

Epidote is not a single mineral. It is a group of related yellowish or greenish minerals but we treat them as one mineral because you would need pretty sophisticated analytical tools to identify them more precisely. Epidote is a metamorphic mineral. By saying that I mean that this mineral as a sand grain is a weathering product of metamorphic rocks.

Tourmaline

Tourmaline is formed in granitic pegmatites. It is a relatively rare mineral in rocks but pretty common in the heavy mineral fraction of most sand samples because of its extreme resistance to weathering. Tourmaline is usually black (variety named schörl) although it could be also brown (dravite) or colorful (elbaite). Tourmaline lacks cleavage. Although tourmaline appears to be black, it is actually translucent. If your microscope has an additional light source below the sample, you can use it to see that black grains become translucent and brown. It distinguishes tourmaline from opaque ilmenite which is also black and may superficially be very similar. However, this method is not too useful to differentiate tourmaline from pyroxenes and hornblendes. Tourmaline has a very strong pleochroism. This property is useful if you have an access to a polarizing microscope.

Olivine

Olivine is usually green and mostly present in volcanic sands. It is the least resistant to weathering among the common heavy minerals. Epidote may sometimes be misidentified as olivine. Weathered olivine may be brown, orange or yellowish.

Garnet

Garnet is very common heavy mineral (actually mineral group) in many sand samples. Most garnets are pink, orange or red. Garnet have isometric crystal structure which means that they are very rarely elongated. Garnets are formed in both metamorphic (schist, amphibolite, eclogite) and igneous (some granites, peridotite) rocks. When sand contains abundant garnet, it usually contains epidote and magnetite as well. Some garnets (pyrope) are useful index minerals when diamond-bearing kimberlite pipes are searched for. Staurolite grains (deeper red color) may be misidentified as garnets.

Sillimanite

Sillimanite is a metamorphic mineral. It occurs mostly in schist and gneiss. It may be present in lesser amount in some granites as an accessory mineral. As a sand grain it usually is accompanied by other metamorphic minerals like kyanite, staurolite, mica, and garnet. It is usually colorless or light brown in color. Sillimanite grains are mostly elongated.

Kyanite

Kyanite is closely related to sillimanite. These two together with andalusite have the same chemical composition but they are different structurally. Kyanite is blue or gray and bladed. It is also a metamorphic mineral like sillimanite.

Staurolite

Staurolite is a metamorphic mineral from medium-grade metamorphic pelitic (parent rocks contained lots of clay) rocks just like kyanite, sillimanite and garnet. They all contain large amount of aluminum. When these minerals are present in sand, you can say with a high degree of certainty that this sand is a weathering product of a metamorphic terrain. Staurolite is brown or reddish brown.

Titanite (sphene)

Titanite is not abundant anywhere but it is present in small amounts in many mostly plutonic (formed deep inside the crust, not volcanic) igneous and some metamorphic rocks. It is often associated with biotite and hornblende. It is not very abundant in sand composition but sometimes you can find characteristically wedge-shaped grains which may have varying color.

Topaz

Topaz is a rare but quite hard (number eight on the Mohs scale) mineral. Most topaz grains crystallized from magma. It is not an easy task to identify topaz. I am pretty sure that most topaz crystals are misidentified and overlooked as ordinary quartz. Topaz is usually colorless.

Zircon

Zircon is one of the most resistant minerals. Oldest zircon crystals are almost as old as the Earth itself. These crystals are the oldest Earth material we know. Meteoritic material is older but it is extraterrestrial in origin. Zircon crystals are generally very small and elongated. They are usually transparent and contain inclusions. It is easy to identify them when using high magnification and illumination from below the sample. Zircons are very resistant but as time goes by they tend to partly destroy themselves by internal radiation. They contain small amount of uranium which may replace zirconium in the crystal strucure. This fact makes zircon grains very valuable to geologists as a geological chronometers.

Apatite

Apatite is present in small quantities in many igneous and metamorphic rocks. It is also an important biomineral. Your teeth, for example, are largely made of this mineral. Apatite crystals are usually elongated and have colorless or pale shades of blueish, greenish or yellowish color.

Monazite

Monazite is an igneous and metamorphic mineral. Monazite grains are usually very small and not easily spotted. They are mostly pale yellow or colorless. Monazite is a valuable mineral resource. It is mined because it contains some rare and valuable chemical elements (cerium, lanthanum, thorium).

Xenotime

Xenotime is related to monazite. It is also valued because of its rare component (yttrium) and some other valuable elements which may replace yttrium in the crystal structure of xenotime. Xenotime is an igneous and metamorphic mineral just like most other minerals described here. It is resistant to weathering and occurs often in the heavy mineral fraction of sands although it is often misidentified as zircon. Xenotime is elongated and usually colorless, yellow or light brown.

Rutile

Rutile occurs in small amounts in igneous and metamorphic rocks. It is a common heavy mineral in sand because it is very resistant to weathering. Rutile is reddish brown and usually elongated. It is easier to spot when the sample is illuminated from below. Rutile is a titanium oxide. It is mined for its titanium content.

Anatase

Anatase has the same composition as rutile. It is also resistant to weathering and comes from igneous rocks or hydrothermally altered veins. Anatase is pretty similar to rutile. It is also mostly deep brown.

Cassiterite

Cassiterite is a tin oxide. Cassiterite comes from igneous rocks or hydrothermally altered veins. Cassiterite is usually brown but it is not easy to identify. Some grains may be twinned in a characteristic way (elbow twins). Cassiterite may be very similar to rutile.

Corundum

Corundum is a very hard mineral (number 9 in the Mohs scale). It is widespread but nowhere abundant. Corundum forms in igneous and metamorphic rocks. It is usually not accompanied by quartz because corundum forms in silica deficient conditions (quartz is silicon oxide – crystallization product of excessive silica). Corundum may be colored in many different shades. Blue corundum is also called sapphire. Red corundum is ruby. Corundum grain usually catches attention because of its unusual color.

Hematite

Hematite is actually very common component of many sands and sandstones but more often not as large sand-sized grains. It is mostly very fine-grained pigment on the surface of other grains. Hematite gives reddish rust-colored hue to many sandstones. Such hematite pigment is deposited from the groundwater moving in the pore space of sand deposits. But larger hematite grains also occur in the heavy mineral fraction of sand.

Ilmenite

Ilmenite is a widespread accessory mineral in many igneous and metamorphic rocks. It is opaque and has a metallic black color. It is weakly magnetic due to intergrown magnetite. Ilmenite grains tend to be somewhat tabular. Ilmenite is mined for its titanium content.

Magnetite

Magnetite is easy to identify because it is very magnetic. Magnetite grains are generally small and equant. Some grains may have well-developed octahedral crystal faces. Magnetite comes from igneous and metamorphic sources.

Chromite

Chromite has the same crystal structure as magnetite but it is only weakly magnetic. Chromite forms in ultramafic igneous rocks. Chromite is an ore of chromium.

I did not mention many minerals which you probably have seen as sand grains. Even my own collection contains many sand samples which are composed almost solely of minerals that are not even mentioned here. These samples are curiosities. I am pretty sure you can walk around the coastline of the entire world looking for a blue sodalite sand without finding it unless you visit specific mines or quarries. Some minerals, like aragonite and calcite are very common components of biogenic sand grains but they usually do not occur as individual sand-forming crystals. Gypsum forms beautiful white sand dunes in New Mexico but is generally not present in sand.

Further reading

Deer, W. A., Howie, R. A. & Zussman, J. (1996). An Introduction to the Rock-Forming Minerals, 2nd Edition. Prentice Hall.

What is sand made of

Sand is usually composed of mineral grains. You’ll find a post about the sand-forming minerals here. Sand itself is not a mineral. It is a sediment just like clay, gravel and silt. Most common sand-forming mineral is quartz. There are two good reasons for that.

Desert sand from Sahara
Desert sand composed almost exclusively of rounded quartz grains. Sand sample is from the Sahara Desert (Erg Murzuk), Libya. Width of view 15 mm.

First, quartz is very important rock-forming mineral. It occurs in many igneous rocks, especially granite. It is also very common component of many metamorphic rocks (quartzite containing little else than quartz). And finally, quartz is a major component of sedimentary rocks, especially sandstone. As these rocks weather and disintegrate, quartz crystals are liberated as sand grains. Another reason why quartz is so widespread in sand is its extreme resistance to weathering. Weakly acidic rain water does not dissolve it effectively and it is also fairly resistant to abrasion.

Despite all of this, quartz is very rarely a sole component of sand. It is accompanied by very many mineral species. First group of them are in sand because they are simply very abundant in rocks. Second group of sand-forming minerals are almost never abundant as rock-formers, but they are, just like quartz, very resistant and therefore their concentration in sand slowly rises as time goes by.

First group contains such widespread minerals as feldspar (more than 50% of the Earth’s crust is composed of feldspars), pyroxene (11% of the crust), and amphibole (5%). They are all mineral groups with a varying chemical composition, unlike quartz, which is a single mineral with definite and very simple chemical composition (SiO2). These minerals, when attacked by weathering agents, relatively quickly disintegrate and they mostly become particles of clay. If we imagine granite, a typical and widespread igneous rock, roughly one third of it is composed of quartz and two thirds is feldspar. When granite disintegrates, quartz becomes sand grains and feldspars are turned to clay. That is the very reason why we have so much of these two sediments and their usually unpleasant mixture with water which we call mud.

Second group consists of sand minerals that are quite unimportant in rocks but remain in sand fraction for a very long time. Such minerals are for example zircon, tourmaline and rutile. Here are some sand-forming minerals: olivine (least resistant), pyroxene, andalusite, sillimanite, amphibole, epidote, sphene (titanite), kyanite, staurolite, chlorite, spinel, garnet, apatite, rutile, tourmaline, zircon. Olivine disintegrates so quickly that we don’t know consolidated sediments older than Quaternary (last few million years) that contain it while zircon grains are the oldest minerals ever found on Earth. Some are almost as old as the Earth itself.

Heavy mineral sand from Sri Lanka which contains lots of different minerals. Width of view 20 mm.

Sand is a very versatile mixture. We have much more than mineral grains in its composition. Third large and versatile group are lithic fragments. They are simply stones that have the size of sand grains. Common rock particles in sand are basalt, granite, schist, sandstone, and limestone which are all very common rock types as well. Therefore we can conclude that stone or rock fragments are an indication that the particular sand sample is not very mature. Otherwise, rocks would have had enough time to disintegrate into single minerals.

This sand sample is composed of volcanic glass (rock fragments) from Punalu’u Beach, Hawaii. Width of view 20 mm.

Fourth important component of many sand types are biogenic fragments. Many marine organisms build hard shells or tests which become sand particles after these organisms die. Most common sand producers are foraminifers, bivalves (clams), gastropods (snails), corals, sea urchins, etc. They are common in low latitude warm sea water, but many species exist in colder water too. In some regions they are so widespread that most beaches are almost entirely composed of these biogenic fragments.

Coral sand from Bermuda. Pink fragments belong to foraminifera. Corals are light-colored. There are also some molluscs and even echinoids (sea urchin spine in the lower left). Width of view 32 mm.

Fifth component of sand are artificial or manmade objects like glass and concrete fragments and plastic pebbles. Definitely we don’t like the growing presence of such sand types although I have to say that some glass sands from former garbage dumps are pretty beautiful and definitely valued as a curiosity by many sand collectors.

http://picasaweb.google.com/107509377372007544953/Coll#5852307320112952114
Sand composed of lithic fragments and rounded pieces of colorful glass. Glass Beach, Kauai, Hawai’i Islands. Width of view 20 mm.

Further reading

Pettijohn, F. J., Potter, P. E. & Siever, R. (1973). Sand and Sandstone. Springer.
Siever, R. (1988). Sand, 2nd Edition. W H Freeman & Co.